HydroHub™
HydroHub™
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Technology reference · sizing

Sizing combined gas for internal combustion engines: why PEM and alkaline aren't interchangeable.

Electrolytically-generated hydrogen and oxygen — oxyhydrogen — has a long, proven track record in combustion enhancement. Traditional alkaline (Brown's Gas) electrolysis is a well-established, effective technology, and at industrial scale — large boilers and thermal plant — it's genuinely well suited to the task. That's not in question here.

This article is about a narrower, more practical issue: how much combined gas an internal combustion engine actually needs, and why the volume specification for that application differs depending on the electrolysis technology producing the gas.

Short answer

Can an alkaline gas-volume benchmark be used to size a PEM system?

No. How much combined gas an internal combustion engine needs for a given effect depends on the purity of the gas delivered as well as on displacement. A contaminated stream carries a smaller effective proportion of active combustion-enhancing gas per unit volume; a clean PEM stream at 99.991% purity does not. A litres-per-hour benchmark established on an alkaline system is therefore not a reliable guide for sizing a PEM system on the same engine — which is why the HydroHub™ range is specified against engine capacity in litres of displacement.

  • Alkaline (Brown's Gas) electrolysis is effective and well suited to industrial-scale plant
  • PEM produces the same H₂/O₂ stream through a solid polymer membrane, not a liquid bath
  • No liquid caustic electrolyte means no electrolyte mist in the gas stream
  • PEM gas purity: 99.991%
  • HydroHub™ units are specified by engine displacement, not by a carried-over gas volume
  • Confirm the unit for a specific engine and duty cycle with a field trial
PEM gas purity
99.991%
PEM electrolyte
Solid polymer membrane
Alkaline electrolyte
Liquid KOH bath
Sizing basis
Engine displacement (L)
1 · Two technologies

Two different volume pictures.

Alkaline electrolysis produces oxyhydrogen using a liquid potassium hydroxide (KOH) electrolyte bath. It scales well to high-volume industrial applications, and decades of use — including our own on-road testing — have established practical volume benchmarks for specific engines and flow rates in that context.

PEM (proton exchange membrane) electrolysis produces the same kind of combined H₂/O₂ stream, but through a different process — a solid polymer membrane rather than a liquid electrolyte bath. One direct consequence: no liquid caustic electrolyte means no electrolyte mist carried into the gas stream, and a resulting gas purity of 99.991%.

PEM compared with alkaline electrolysis for combined-gas sizing on internal combustion engines
CriterionPEMAlkaline (Brown's Gas)
ElectrolyteSolid polymer membraneLiquid potassium hydroxide (KOH) bath
Gas purity99.991% — no electrolyte mist carry-overElectrolyte mist carry-over is a known handling issue
Scale it suits bestMobile and on-engine applicationsHigh-volume industrial plant and large boilers
Sizing basis used hereEngine capacity (litres of displacement)Established gas-volume / flow-rate benchmarks
Effective active gas per unit volumeFull — the stream is the productReduced by whatever is carried with the stream
Track recordCurrent HydroHub rangeDecades of use, including our own on-road testing
2 · Why this matters for sizing an ICE system

Purity changes the effective volume.

For internal combustion engines specifically, the question that matters is: how much combined gas does the engine actually need for a given effect? That answer isn't just a function of engine displacement — it also depends on the purity of the gas being delivered.

A contaminated stream carries a smaller effective proportion of active combustion-enhancing gas per unit volume; a clean, high-purity PEM stream doesn't. That means a volume benchmark established on an alkaline system isn't a reliable guide for sizing a PEM system for the same engine — treating the two as directly interchangeable on a litres-per-hour basis risks over- or under-sizing the unit for the application.

This is why our PEM product range is specified against engine capacity (litres of displacement) rather than against a fixed gas-volume benchmark carried over from alkaline systems — the sizing logic has to account for the technology actually producing the gas.

HydroHub™ PEM range with the engine displacement band each unit is specified against
HydroHub™ A-450HydroHub™ A-675HydroHub™ A-900HydroHub™ H-PowerHydroHub™ DH-Power
1.0 – 1.8 L2.0 – 2.5 L2.7 – 7.0 LUp to 7.0 LUp to 16.0 L

Full specifications side by side on compare systems.

3 · The right way to confirm sizing

Measure it on the actual equipment.

As with any combustion-enhancement application, the most reliable way to confirm the right unit for a specific engine and duty cycle is a field trial — measuring real results on the actual equipment, rather than assuming a figure from a different technology carries across unchanged.

No projected, typical or expected fuel-saving figure is published. Actual results vary materially with engine condition, duty cycle, load profile, fuel quality, installation and operating conditions. A controlled field evaluation on your own equipment, with baseline data captured before installation, is required before any commercial projection.

FAQ

Questions.

Is alkaline electrolysis a bad technology?

No. Traditional alkaline (Brown's Gas) electrolysis is a well-established, effective technology with a long track record in combustion enhancement, and at industrial scale — large boilers and thermal plant — it is genuinely well suited to the task. That is not in question. The narrower point on this page is about how the volume specification for an internal combustion engine differs depending on which technology produces the gas.

Why can't I use an alkaline litres-per-hour figure to size a PEM unit?

Because how much combined gas an engine needs for a given effect is not purely a function of displacement — it also depends on the purity of the gas delivered. A contaminated stream carries a smaller effective proportion of active combustion-enhancing gas per unit volume; a clean, high-purity PEM stream does not. Treating the two as directly interchangeable on a litres-per-hour basis risks over- or under-sizing the unit for the application.

What purity does PEM deliver?

99.991%. There is no liquid caustic electrolyte in a PEM cell, so there is no electrolyte mist to be carried into the gas stream.

So how is the HydroHub™ range specified?

Against engine capacity — litres of displacement — rather than against a fixed gas-volume benchmark carried over from alkaline systems. The sizing logic has to account for the technology actually producing the gas.

How do I confirm the right unit for my engine?

A field trial. As with any combustion-enhancement application, the most reliable confirmation is measuring real results on the actual equipment and duty cycle, rather than assuming a figure from a different technology carries across unchanged.
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